576-3 | Formulation | Materials and Chemistry | S8 | ||||||
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Lessons : 14 h | TD : 7 h | TP : 0 h | Project : 0 h | Total : 21 h | |||||
Co-ordinator : Luc PICTON |
Prerequisite | |
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Basic knowledge about polymers | |
Course Objectives | |
Introduction to formulation: Scattered systems (suspension, emulsions, foams), rheology | |
Syllabus | |
Formulation: history, definition, specifications Presentation of attractive, repulsive forces at play, notion of stability/instability Thermodynamic and/or kinetic medium of action (Rheology) Scattered systems: colloidal stability, molecule or polymer adsorption, anchor point, steric and/or electrostatic stabilization. Sample study Emulsion: example, surface tension, Laplace law, wettability (Young-Dupré's law), tensioactives, role of tensioactives in formulation (emulsifier, stabilizer, detergent, foaming agent, wettability agent, rheological agent, agent transport). Sample study Rheology: context, definition, tools - Permanent mode or flow (Newtonian behavior, non Newtonian rheofluidifying or thickening, thixotropy, stress-threshold fluid. - Transitional mode (creep), - Dynamic mode (oscillations): linear viscoelasticity |
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Practical work (TD or TP) | |
Summary of the previous course presented by students at the beginning of the following course 10-minute presentations on a formulation chosen by a pair or a trinôme |
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Acquired skills | |
Base in formulation and on mechanisms and tools to control the stability and instability of dispersed systems and emulsions. Acquiring the basics in rheology | |
Bibliography | |
Techniques de l’Ingénieur |
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