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Formulation

576-3 Formulation Materials and Chemistry S8
Lessons : 14 h TD : 7 h TP : 0 h Project : 0 h Total : 21 h
Co-ordinator : Luc PICTON
Prerequisite
Basic knowledge about polymers
Course Objectives
Introduction to formulation: Scattered systems (suspension, emulsions, foams), rheology
Syllabus
Formulation: history, definition, specifications

Presentation of attractive, repulsive forces at play, notion of stability/instability

Thermodynamic and/or kinetic medium of action (Rheology)

Scattered systems: colloidal stability, molecule or polymer adsorption, anchor point, steric and/or electrostatic stabilization. Sample study

Emulsion: example, surface tension, Laplace law, wettability (Young-Dupré's law), tensioactives, role of tensioactives in formulation (emulsifier, stabilizer, detergent, foaming agent, wettability agent, rheological agent, agent transport). Sample study

Rheology: context, definition, tools
- Permanent mode or flow (Newtonian behavior, non Newtonian rheofluidifying or thickening, thixotropy, stress-threshold fluid.
- Transitional mode (creep),
- Dynamic mode (oscillations): linear viscoelasticity
Practical work (TD or TP)
Summary of the previous course presented by students at the beginning of the following course
10-minute presentations on a formulation chosen by a pair or a trinôme

Acquired skills
Base in formulation and on mechanisms and tools to control the stability and instability of dispersed systems and emulsions. Acquiring the basics in rheology
Bibliography
Techniques de l’Ingénieur

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