566-3 | Rearrangements et pericyclic process | Materials and Chemistry | S7 | ||||||
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Lessons : 14 h | TD : 7 h | TP : 0 h | Project : 0 h | Total : 21 h | |||||
Co-ordinator : Olivier Delacroix |
Prerequisite | |
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First year program in organic chemistry | |
Course Objectives | |
Syllabus | |
* Frontier orbitals in organic chemistry: Description of orbitals by the extended Hückel and Hückel method Frost and Musulin diagrams Definition of frontier orbitals Illustrations of their use in electrocyclic reactions (Woodward-Hoffman rules), sigmatropic reactions, 4pi + 2pi cycloaddition reactions (Diels-Alder and 1,3-dipolar) * Non-pericyclic rearrangement reactions |
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Practical work (TD or TP) | |
Molecular modeling of a chemical reaction | |
Acquired skills | |
Bibliography | |
Organic chemistry (S. Warren/ J. Clayden) Molecular orbital and organic chemical reaction (I. Fleming) |
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