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Rearrangements et pericyclic process

566-3 Rearrangements et pericyclic process Materials and Chemistry S7
Lessons : 14 h TD : 7 h TP : 0 h Project : 0 h Total : 21 h
Co-ordinator : Olivier Delacroix
Prerequisite
First year program in organic chemistry
Course Objectives
Syllabus
* Frontier orbitals in organic chemistry:
Description of orbitals by the extended Hückel and Hückel method
Frost and Musulin diagrams
Definition of frontier orbitals
Illustrations of their use in electrocyclic reactions (Woodward-Hoffman rules), sigmatropic reactions, 4pi + 2pi cycloaddition reactions (Diels-Alder and 1,3-dipolar)
* Non-pericyclic rearrangement reactions

Practical work (TD or TP)
Molecular modeling of a chemical reaction
Acquired skills
Bibliography
Organic chemistry (S. Warren/ J. Clayden)
Molecular orbital and organic chemical reaction (I. Fleming)

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